Nothing stopping you setting up Pi-Hole. Disable the DHCP server in the BT Hub and enable the DHCP server in Pi-Hole.
It's not ideal I'll admit but it's doable.
Tried that, everything thats on my network with a physical cable connection worked fine, but all the wireless stuff just wouldnt get an IP address.
Pihole shows no requests for addresses, soon as i switch the router dhcp back on everything works again.
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